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How are surface tension related to viscosity?

Jan 15, 2021

First, liquid surface tension and viscosity share a common characteristic: they both relate to the properties of the fluid. After that, things start to get blurry.
Let's start with surface tension. This involves surface tension - the property of a liquid surface that floats paper against; it acts as a barrier to foreign matter and also holds the liquid together. This unique property is caused by unbalanced forces on surface molecules that pull toward the main part of the liquid.
Viscosity, on the other hand, is related to viscosity shear rate, a liquid's resistance to being deformed or moved. This is caused by friction between molecules.

Surface tension is a simpler phenomenon than viscosity. It is essentially stable and is modified primarily by temperature and chemicals that alter the bonding properties of the molecule. As the temperature decreases, the surface tension n increases. The effect of adding unrelated substances is exemplified by putting soap (surfactant) into water to lower surface tension, which allows dirt on your hands to mix more easily with the water.

When it comes to viscosity, it's important to know the type of liquid. For example, there are Newtonian fluids that respond to forces (sometimes called shear rate) that move the fluid in a straight, linear fashion (sometimes called shear stress).

However, non-Newtonian fluids follow a different set of rules. As pressure or force increases, the viscosity of a shear-thinning fluid decreases. Thixotropic fluids change viscosity over time - such as gels and colloids, and yes, ketchup is stable when at rest but becomes fluid when agitated.

So we see that finding the true value of viscosity (which some of us may think is just thickness) is a complex process. Unlike surface tension, which is often a static phenomenon, viscosity is at its most viscous and is in motion. Everything about measuring surface tension should concern whether we use Wilhelmy plates or duNouy rings.

The last question should probably be the first question, regarding the relationship between surface tension and viscosity. You might think that a thick fluid would translate into high surface tension and a thin fluid would result in lower surface tension. wrong. In fact, my research shows that there is no definite correlation.

When I first considered taking what seemed like a simple comparison of international numbers, it was more than a theoretical tangle. However, the answer is clear: no correlation. The reason is not that simple. I think a good summary is that surface tension is about steady state and viscosity is about motion.

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